| Business | Phone |
| Vocational Agricultural Dept 324 Liberty St, Chaffee 63740 | (573) 794-2456 |
| St Ambrose Catholic School 419 S 3rd St, Chaffee 63740 | (573) 887-6711 |
| Scott County Ii School Dist 517 W Yoakum Ave, Chaffee 63740 | (573) 887-3532 |
| Chaffee Elementary School 408 Elliott Ave, Chaffee 63740 | (573) 887-3244 |
| Chaffee Head Start 611 N Main St, Chaffee 63740 | (573) 887-6220 |
| Chaffee Public Schools 109 N 5th St, Chaffee 63740 | (573) 887-3532 |
| Chaffee School 517 W Yoakum Ave, Chaffee 63740 | (573) 887-3226 |