| Business | Phone |
| Immanuel Lutheran School 225 W South St, Perryville 63775 | (573) 547-6161 |
| Parish School Of Religion 1010 Rosati Ct, Perryville 63775 | (573) 547-4591 |
| Perry County School Dist 307 Rolla St, Perryville 63775 | (573) 547-7500 |
| Perry County School Dist 32 326 College St, Perryville 63775 | (573) 547-4939 |
| Perryville Area Higher Ed Ctr 108 S Progress Dr, Perryville 63775 | (573) 547-4143 |
| St Vincent Elementary School 1007 W Saint Joseph St, Perryville 63775 | (573) 547-6503 |
| St Vincent High School 210 S Waters St, Perryville 63775 | (573) 547-2560 |