| Business | Phone |
| Adams County Brd-Mental Rtrdtn 3964 Wheat Ridge Rd, West Union 45693 | (937) 544-2574 |
| Adams County Christian Schools 187 Willow Dr, West Union 45693 | (937) 544-5502 |
| Adams County Ohio Valley Dist 141 Lloyd Rd, West Union 45693 | (937) 544-5586 |
| Adams County Special Education 285 Lloyd Rd, West Union 45693 | (937) 544-1665 |
| Intervention School 159 Lloyd Rd, West Union 45693 | (937) 544-4431 |
| Ohio Valley Career & Tech Center 175 Lloyd Rd, West Union 45693 | (937) 544-2336 |
| West Union Elementary School 201 W South St, West Union 45693 | (937) 544-2951 |
| West Union High School 97 Dragon Lair Dr, West Union 45693 | (937) 544-5553 |
| Tiffin Preschool 11827 State Route 125, West Union 45693 | (937) 544-5374 |
| Safeway Driver Education Schl 9754 State Route 41, West Union 45693 | (937) 544-5499 |