| Business | Phone |
| Comanche Special Svc Co-Op 217 N Texas St, De Leon 76444 | (254) 893-2130 |
| Perkins Middle School 616 N Johnson St, De Leon 76444 | (254) 893-6111 |
| De Leon Elementary School 133 E Pecan Ave, De Leon 76444 | (254) 893-6889 |
| De Leon High School 610 N Johnson St, De Leon 76444 | (254) 893-5474 |
| De Leon High School 708 N Johnson St, De Leon 76444 | (254) 893-6222 |
| De Leon Isd Alternative De Leon 76444 | (254) 893-4429 |
| De Leon Superintendent Office 601 S Houston St, De Leon 76444 | (254) 893-5095 |