| Business | Phone |
| Natalia Elementary School 8th St & Pearson Stamp;, Natalia 78059 | (830) 663-2837 |
| Natalia Headstart 1360 State Highway 132 N, Natalia 78059 | (830) 663-9739 |
| Natalia High School 1360 State Highway 132 N, Natalia 78059 | (830) 663-4417 |
| Natalia Junior High School 8th St & Pearson Stamp;, Natalia 78059 | (830) 663-4027 |
| Natalia Special Edu 9th & Milleramp;, Natalia 78059 | (830) 663-5603 |
| Natalia Superintendent's Ofc 8th & Pearson Stamp;, Natalia 78059 | (830) 663-4416 |