| Business | Phone |
| Old Dominion University 3441 Mountain Empire Rd 150, Big Stone Gap 24219 | (276) 523-8294 |
| Powell Valley High School 1 Avenue Of Champions, Big Stone Gap 24219 | (276) 523-1290 |
| Powell Valley Middle School 3137 2nd Ave E, Big Stone Gap 24219 | (276) 523-0195 |
| Powell Valley Primary School 2945 2nd Ave E, Big Stone Gap 24219 | (276) 523-4900 |