| Business | Phone |
| Glenwood School 1734 Glenwood Park Rd, Princeton 24740 | (304) 425-2445 |
| Knob Elementary School 706 Knob St, Princeton 24740 | (304) 425-3171 |
| Melrose Elementary School 257 Athens Rd, Princeton 24740 | (304) 425-3757 |
| Mercer Christian Academy 314 Oakvale Rd # A, Princeton 24740 | (304) 425-5671 |
| Mercer Christian Academy 314 Oakvale Rd A, Princeton 24740 | (304) 487-1603 |
| Mercer County Academy Of Adult 195 Davis St, Princeton 24740 | (304) 425-7953 |
| Mercer County Board-Education 1403 Honaker Ave, Princeton 24740 | (304) 487-1551 |
| Mercer Elementary School 1200 Mercer St, Princeton 24740 | (304) 425-3160 |
| Pikeview High School 3566 Eads Mill Rd, Princeton 24740 | (304) 384-7586 |
| Princeton High School 1321 Stafford Dr, Princeton 24740 | (304) 425-8101 |
| Princeton Middle School 300 N Johnston St, Princeton 24740 | (304) 425-7517 |
| Princeton Primary School 219 Old Bluefield Rd B, Princeton 24740 | (304) 487-3904 |
| Silver Springs Early Learning 821 Broadway St, Princeton 24740 | (304) 425-4251 |
| Straley Elementary School 810 Straley Ave, Princeton 24740 | (304) 425-3173 |
| Thorn Elementary School 219 Old Bluefield Rd B, Princeton 24740 | (304) 425-3172 |